Moore G E 1998 Cramming more components onto integrated circuits Proc. IEEE 86 82–5 |
Salahuddin S, Ni K and Datta S 2018 The era of hyper-scaling in electronics Nat. Electron. 1 442–50 |
Chen Y, Shu Z, Zhang S, Zeng P, Liang H, Zheng M and Duan H 2021 Sub-10 nm fabrication: methods and applications Int. J. Extreme Manuf. 3 032002 |
Yang Y, Gu C and Li J 2019 Sub-5 nm metal nanogaps: physical properties, fabrication methods, and device applications Small 15 e1804177 |
Fang F, Zhang N, Guo D, Ehmann K, Cheung B, Liu K and Yamamura K 2019 Towards atomic and close-to-atomic scale manufacturing Int. J. Extreme Manuf. 1 012001 |
Luo S, Mancini A, Berte R, Hoff B H, Maier S A and de Mello J C 2021 Massively parallel arrays of size-controlled metallic nanogaps with gap-widths down to the sub-3-nm level Adv. Mater. 33 e2100491 |
Luo S, Hoff B H, Maier S A and de Mello J C 2021 Scalable fabrication of metallic nanogaps at the sub-10 nm level Adv. Sci. 8 2102756 |
Liu J et al 2019 Transition from tunneling leakage current to molecular tunneling in single-molecule junctions Chemistry 5 390–401 |
Peercy P S 2000 The drive to miniaturization Nature 406 1023–6 |
van Ruitenbeek J M 2016 Molecular electronics: a brief overview of the status of the field Single-Molecule Electronics: An Introduction to Synthesis, Measurement and Theory ed M Kiguchi (Singapore: Springer Singapore) pp 1–23 |
Xiang D, Wang X L, Jia C C, Lee T and Guo X F 2016 Molecular-scale electronics: from concept to function Chem. Rev. 116 4318–440 |
Xin N, Guan J, Zhou C, Chen X, Gu C, Li Y, Ratner M A, Nitzan A, Stoddart J F and Guo X 2019 Concepts in the design and engineering of single-molecule electronic devices Nat. Rev. Phys. 1 211–30 |
Su T A, Neupane M, Steigerwald M L, Venkataraman L and Nuckolls C 2016 Chemical principles of single-molecule electronics Nat. Rev. Mater. 1 16002 |
Chen H L and Stoddart J F 2021 From molecular to supramolecular electronics Nat. Rev. Mater. 6 804–28 |
Gehring P, Thijssen J M and van der Zant H S J 2019 Single-molecule quantum-transport phenomena in break junctions Nat. Rev. Phys. 1 381–96 |
Sun L, Diaz-Fernandez Y A, Gschneidtner T A, Westerlund F, Lara-Avila S and Moth-Poulsen K 2014 Single-molecule electronics: from chemical design to functional devices Chem. Soc. Rev. 43 7378–411 |
Cui A, Dong H and Hu W 2015 Nanogap electrodes towards solid state single-molecule transistors Small 11 6115–41 |
Tsutsui M and Taniguchi M 2012 Single molecule electronics and devices Sensors 12 7259–729 |
Bai J, Li X, Zhu Z, Zheng Y and Hong W 2021 Single-molecule electrochemical transistors Adv. Mater. 33 2005883 |
Hong C, Yang S and Ndukaife J C 2020 Stand-off trapping and manipulation of sub-10 nm objects and biomolecules using opto-thermo-electrohydrodynamic tweezers Nat. Nanotechnol. 15 908–13 |
Wang T and Nijhuis C A 2016 Molecular electronic plasmonics Appl. Mater. Today 3 73–86 |
Chen L J, Feng A N, Wang M N, Liu J Y, Hong W J, Guo X F and Xiang D 2018 Towards single-molecule optoelectronic devices Sci. China-Chem. 61 1368–84 |
Barla P, Joshi V K and Bhat S 2021 Spintronic devices: a promising alternative to CMOS devices J. Comput. Electron. 20 805–37 |
Komoto Y, Fujii S, Iwane M and Kiguchi M 2016 Single-molecule junctions for molecular electronics J. Mater. Chem. C 4 8842–58 |
Lu Z, Zheng J, Shi J, Zeng B-F, Yang Y, Hong W and Tian Z-Q 2021 Application of micro/nanofabrication techniques to on-chip molecular electronics Small Methods 5 2001034 |
Evers F, Korytár R, Tewari S and van Ruitenbeek J M 2020 Advances and challenges in single-molecule electron transport Rev. Mod. Phys. 92 035001 |
Makk P, Tomaszewski D, Martinek J, Balogh Z, Csonka S, Wawrzyniak M, Frei M, Venkataraman L and Halbritter A 2012 Correlation analysis of atomic and single-molecule junction conductance ACS Nano 6 3411–23 |
Haiss W, Nichols R J, van Zalinge H, Higgins S J, Bethell D and Schiffrin D J 2004 Measurement of single molecule conductivity using the spontaneous formation of molecular wires Phys. Chem. Chem. Phys. 6 4330–7 |
Haiss W, van Zalinge H, Higgins S J, Bethell D, Höbenreich H, Schiffrin D J and Nichols R J 2003 Redox state dependence of single molecule conductivity J. Am. Chem. Soc. 125 15294–5 |
Xu B and Tao N 2003 Measurement of single-molecule resistance by repeated formation of molecular junctions Science 301 1221–3 |
Venkataraman L, Klare J E, Nuckolls C, Hybertsen M S and Steigerwald M L 2006 Dependence of single-molecule junction conductance on molecular conformation Nature 442 904–7 |
Garner M H et al 2018 Comprehensive suppression of single-molecule conductance using destructive sigma-interference Nature 558 415–9 |
Huang Z, Xu B, Chen Y, Ventra M D and Tao N 2006 Measurement of current-induced local heating in a single molecule junction Nano Lett. 6 1240–4 |
Xu B, Xiao X and Tao N J 2003 Measurements of single-molecule electromechanical properties J. Am. Chem. Soc. 125 16164–5 |
Frei M, Aradhya S V, Hybertsen M S and Venkataraman L 2012 Linker dependent bond rupture force measurements in single-molecule junctions J. Am. Chem. Soc. 134 4003–6 |
Aradhya S V, Frei M, Hybertsen M S and Venkataraman L 2012 Van der Waals interactions at metal/organic interfaces at the single-molecule level Nat. Mater. 11 872–6 |
Lumbroso O S, Simine L, Nitzan A, Segal D and Tal O 2018 Electronic noise due to temperature differences in atomic-scale junctions Nature 562 240–4 |
Hong W, Li H, Liu S, Fu Y, Li J, Kaliginedi V, Decurtins S and Wandlowski T 2012 Trimethylsilyl-terminated oligo(phenylene ethynylene)s: an approach to single-molecule junctions with covalent Au-C sigma-bonds J. Am. Chem. Soc. 134 19425–31 |
Reed M A, Zhou C, Muller C J, Burgin T P and Tour J M 1997 Conductance of a molecular junction Science 278 252–4 |
Zhou C, Muller C J, Deshpande M R, Sleight J W and Reed M A 1995 Microfabrication of a mechanically controllable break junction in silicon Appl. Phys. Lett. 67 1160–2 |
Huber R et al 2008 Electrical conductance of conjugated oligomers at the single molecule level J. Am. Chem. Soc. 130 1080–4 |
Dubois V, Raja S N, Gehring P, Caneva S, van der Zant H S J, Niklaus F and Stemme G 2018 Massively parallel fabrication of crack-defined gold break junctions featuring sub-3 nm gaps for molecular devices Nat. Commun. 9 3433 |
Frisenda R, Janssen V A E C, Grozema F C, van der Zant H S J and Renaud N 2016 Mechanically controlled quantum interference in individual π-stacked dimers Nat. Chem. 8 1099–104 |
Lörtscher E, Ciszek J W, Tour J and Riel H 2006 Reversible and controllable switching of a single-molecule junction Small 2 973–7 |
Lörtscher E, Gotsmann B, Lee Y, Yu L, Rettner C and Riel H 2012 Transport properties of a single-molecule diode ACS Nano 6 4931–9 |
Jeong H, Domulevicz L K and Hihath J 2021 Design and fabrication of a MEMS-based break junction device for mechanical strain-correlated optical characterization of a single-molecule J. Microelectromech. Syst. 30 126–36 |
Jeong H, Li H B, Domulevicz L and Hihath J 2020 An on-chip break junction system for combined single-molecule conductance and Raman spectroscopies Adv. Funct. Mater. 30 2000615 |
Song H, Kim Y, Jang Y H, Jeong H, Reed M A and Lee T 2009 Observation of molecular orbital gating Nature 462 1039–43 |
Hoffmann-Vogel R 2017 Electromigration and the structure of metallic nanocontacts Appl. Phys. Rev. 4 031302 |
Kim Y, Ang C H, Ang K and Chang S W 2021 Electromigrated nanogaps: a review on the fabrications and applications J. Vac. Sci. Technol. B 39 010802 |
Park H, Lim A K L, Alivisatos A P, Park J and McEuen P L 1999 Fabrication of metallic electrodes with nanometer separation by electromigration Appl. Phys. Lett. 75 301–3 |
Ward D R, Corley D A, Tour J M and Natelson D 2011 Vibrational and electronic heating in nanoscale junctions Nat. Nanotechnol. 6 33–38 |
Qin L, Park S, Huang L and Mirkin Chad A 2005 On-wire lithography Science 309 113–5 |
Guo X et al 2006 Covalently bridging gaps in single-walled carbon nanotubes with conducting molecules Science 311 356 |
Guo X and Nuckolls C 2009 Functional single-molecule devices based on SWNTs as point contacts J. Mater. Chem. 19 5470–3 |
Qi P, Javey A, Rolandi M, Wang Q, Yenilmez E and Dai H 2004 Miniature organic transistors with carbon nanotubes as quasi-one-dimensional electrodes J. Am. Chem. Soc. 126 11774–5 |
Wei D, Liu Y, Cao L, Wang Y, Zhang H and Yu G 2008 Real time and in situ control of the gap size of nanoelectrodes for molecular devices Nano Lett. 8 1625–30 |
Cao Y, Dong S, Liu S, He L, Gan L, Yu X, Steigerwald M L, Wu X, Liu Z and Guo X 2012 Building high-throughput molecular junctions using indented graphene point contacts Angew. Chem., Int. Ed. 51 12228–32 |
Prins F, Barreiro A, Ruitenberg J W, Seldenthuis J S, Aliaga-Alcalde N, Vandersypen L M K and van der Zant H S J 2011 Room-temperature gating of molecular junctions using few-layer graphene nanogap electrodes Nano Lett. 11 4607–11 |
Caneva S, Gehring P, García-Suárez V M, García-Fuente A, Stefani D, Olavarria-Contreras I J, Ferrer J, Dekker C and van der Zant H S J 2018 Mechanically controlled quantum interference in graphene break junctions Nat. Nanotechnol. 13 1126–31 |
Chen F, Li X, Hihath J, Huang Z and Tao N 2006 Effect of anchoring groups on single-molecule conductance: comparative study of thiol-, amine-, and carboxylic-acid-terminated molecules J. Am. Chem. Soc. 128 15874–81 |
Hong W, Manrique D Z, Moreno-García P, Gulcur M, Mishchenko A, Lambert C J, Bryce M R and Wandlowski T 2012 Single molecular conductance of tolanes: experimental and theoretical study on the junction evolution dependent on the anchoring group J. Am. Chem. Soc. 134 2292–304 |
Di Ventra M and Taniguchi M 2016 Decoding DNA, RNA and peptides with quantum tunnelling Nat. Nanotechnol. 11 117–26 |
Guo C, Yu X, Refaely-Abramson S, Sepunaru L, Bendikov T, Pecht I, Kronik L, Vilan A, Sheves M and Cahen D 2016 Tuning electronic transport via hepta-alanine peptides junction by tryptophan doping Proc. Natl Acad. Sci. USA 113 10785 |
Yang C et al 2021 Electric field–catalyzed single-molecule Diels-Alder reaction dynamics Sci. Adv. 7 eabf0689 |
Li P, Jia C and Guo X 2021 Structural transition dynamics in carbon electrode-based single-molecule junctions Chin. J. Chem. 39 223–31 |
Schoonveld W A, Wildeman J, Fichou D, Bobbert P A, van Wees B J and Klapwijk T M 2000 Coulomb-blockade transport in single-crystal organic thin-film transistors Nature 404 977–80 |
Park J et al 2002 Coulomb blockade and the Kondo effect in single-atom transistors Nature 417 722–5 |
Pasupathy A N, Bialczak R C, Martinek J, Grose J E, Donev L A K, McEuen P L and Ralph D C 2004 The Kondo effect in the presence of ferromagnetism Science 306 86–89 |
Bai J et al 2019 Anti-resonance features of destructive quantum interference in single-molecule thiophene junctions achieved by electrochemical gating Nat. Mater. 18 364–9 |
Huang B et al 2018 Controlling and observing sharp-valleyed quantum interference effect in single molecular junctions J. Am. Chem. Soc. 140 17685–90 |
Li Y et al 2019 Gate controlling of quantum interference and direct observation of anti-resonances in single molecule charge transport Nat. Mater. 18 357–63 |
Liu J, Huang X, Wang F and Hong W 2019 Quantum interference effects in charge transport through single-molecule junctions: detection, manipulation, and application Acc. Chem. Res. 52 151–60 |
Lee W, Kim K, Jeong W, Zotti L A, Pauly F, Cuevas J C and Reddy P 2013 Heat dissipation in atomic-scale junctions Nature 498 209–12 |
Mosso N, Drechsler U, Menges F, Nirmalraj P, Karg S, Riel H and Gotsmann B 2017 Heat transport through atomic contacts Nat. Nanotechnol. 12 430–3 |
Cui L, Jeong W, Hur S, Matt M, Klöckner J C, Pauly F, Nielaba P, Cuevas J C, Meyhofer E and Reddy P 2017 Quantized thermal transport in single-atom junctions Science 355 1192–5 |
Cui L, Hur S, Akbar Z A, Klöckner J C, Jeong W, Pauly F, Jang S-Y, Reddy P and Meyhofer E 2019 Thermal conductance of single-molecule junctions Nature 572 628–33 |
Tsutsui M, Morikawa T, He Y, Arima A and Taniguchi M 2015 High thermopower of mechanically stretched single-molecule junctions Sci. Rep. 5 11519 |
Morikawa T, Arima A, Tsutsui M and Taniguchi M 2014 Thermoelectric voltage measurements of atomic and molecular wires using microheater-embedded mechanically-controllable break junctions Nanoscale 6 8235–41 |
Tsutsui M, Morikawa T, Arima A and Taniguchi M 2013 Thermoelectricity in atom-sized junctions at room temperatures Sci. Rep. 3 3326 |
Tsutsui M, Kawai T and Taniguchi M 2012 Unsymmetrical hot electron heating in quasi-ballistic nanocontacts Sci. Rep. 2 217 |
Emberly E G and Kirczenow G 2002 Molecular spintronics: spin-dependent electron transport in molecular wires Chem. Phys. 281 311–24 |
Li H, Shi W, Song J, Jang H-J, Dailey J, Yu J and Katz H E 2019 Chemical and biomolecule sensing with organic field-effect transistors Chem. Rev. 119 3–35 |
Zhang C, Chen P and Hu W 2015 Organic field-effect transistor-based gas sensors Chem. Soc. Rev. 44 2087–107 |
Reecht G, Scheurer F, Speisser V, Dappe Y J, Mathevet F and Schull G 2014 Electroluminescence of a polythiophene molecular wire suspended between a metallic surface and the tip of a scanning tunneling microscope Phys. Rev. Lett. 112 047403 |
Schwarz F and Lörtscher E 2014 Break-junctions for investigating transport at the molecular scale J. Phys.-Condes. Matter 26 474201 |
Khoo K H, Chen Y, Li S and Quek S Y 2015 Length dependence of electron transport through molecular wires—a first principles perspective Phys. Chem. Chem. Phys. 17 77–96 |
McCreery R L 2004 Molecular electronic junctions Chem. Mater. 16 4477–96 |
Scholes G D et al 2017 Using coherence to enhance function in chemical and biophysical systems Nature 543 647–56 |
Fano U 1961 Effects of configuration interaction on intensities and phase shifts Phys. Rev. 124 1866–78 |
Hong W, Valkenier H, Mészáros G, Manrique D Z, Mishchenko A, Putz A, García P M, Lambert C J, Hummelen J C and Wandlowski T 2011 An MCBJ case study: the influence of π-conjugation on the single-molecule conductance at a solid/liquid interface Beilstein J. Nanotechnol. 2 699–713 |
Yang G et al 2017 Protonation tuning of quantum interference in azulene-type single-molecule junctions Chem. Sci. 8 7505–9 |
Zhang Y-P et al 2018 Distinguishing diketopyrrolopyrrole isomers in single-molecule junctions via reversible stimuli-responsive quantum interference J. Am. Chem. Soc. 140 6531–5 |
Jeong H, Kim D, Xiang D and Lee T 2017 High-yield functional molecular electronic devices ACS Nano 11 6511–48 |
Vilan A, Aswal D and Cahen D 2017 Large-area, ensemble molecular electronics: motivation and challenges Chem. Rev. 117 4248–86 |
Zheng H, Jiang F, He R, Yang Y, Shi J and Hong W 2019 Charge transport through peptides in single-molecule electrical measurements Chin. J. Chem. 37 1083–96 |
Liu Z et al 2011 Revealing the molecular structure of single-molecule junctions in different conductance states by fishing-mode tip-enhanced Raman spectroscopy Nat. Commun. 2 305 |
Tian J H, Liu B, Li X, Yang Z L, Ren B, Wu S T, Tao N and Tian Z Q 2006 Study of molecular junctions with a combined surface-enhanced Raman and mechanically controllable break junction method J. Am. Chem. Soc. 128 14748–9 |
Akkerman H B, Blom P W M, de Leeuw D M and de Boer B 2006 Towards molecular electronics with large-area molecular junctions Nature 441 69–72 |
Holmlin R E, Haag R, Chabinyc M L, Ismagilov R F, Cohen A E, Terfort A, Rampi M A and Whitesides G M 2001 Electron transport through thin organic films in metal−insulator−metal junctions based on self-assembled monolayers J. Am. Chem. Soc. 123 5075–85 |
Chiechi R C, Weiss E A, Dickey M D and Whitesides G M 2008 Eutectic gallium–indium (EGaIn): a moldable liquid metal for electrical characterization of self-assembled monolayers Angew. Chem., Int. Ed. 47 142–4 |
Feldman A K, Steigerwald M L, Guo X and Nuckolls C 2008 Molecular electronic devices based on single-walled carbon nanotube electrodes Acc. Chem. Res. 41 1731–41 |
Ghasemi S and Moth-Poulsen K 2021 Single molecule electronic devices with carbon-based materials: status and opportunity Nanoscale 13 659–71 |
Jia C, Ma B, Xin N and Guo X 2015 Carbon electrode–molecule junctions: a reliable platform for molecular electronics Acc. Chem. Res. 48 2565–75 |
Black J R 1969 Electromigration—a brief survey and some recent results IEEE Trans. Electron Devices 16 338–47 |
Houck A A, Labaziewicz J, Chan E K, Folk J A and Chuang I L 2005 Kondo effect in electromigrated gold break junctions Nano Lett. 5 1685–8 |
Esen G and Fuhrer M S 2005 Temperature control of electromigration to form gold nanogap junctions Appl. Phys. Lett. 87 263101 |
Strachan D R, Smith D E, Johnston D E, Park T H, Therien M J, Bonnell D A and Johnson A T 2005 Controlled fabrication of nanogaps in ambient environment for molecular electronics Appl. Phys. Lett. 86 043109 |
Hoffmann R, Weissenberger D, Hawecker J and Stöffler D 2008 Conductance of gold nanojunctions thinned by electromigration Appl. Phys. Lett. 93 043118 |
Campbell J M and Knobel R G 2013 Feedback-controlled electromigration for the fabrication of point contacts Appl. Phys. Lett. 102 023105 |
Johnston D E, Strachan D R and Johnson A T C 2007 Parallel fabrication of nanogap electrodes Nano Lett. 7 2774–7 |
Suga H, Suzuki H, Otsu K, Abe T, Umeta Y, Tsukagoshi K, Sumiya T, Shima H, Akinaga H and Naitoh Y 2020 Feedback electromigration assisted by alternative voltage operation for the fabrication of facet-edge nanogap electrodes ACS Appl. Nano Mater. 3 4077–83 |
O’Neill K, Osorio E A and van der Zant H S J 2007 Self-breaking in planar few-atom Au constrictions for nanometer-spaced electrodes Appl. Phys. Lett. 90 133109 |
Prins F, Hayashi T, de Vos van Steenwijk B J A, Gao B, Osorio E A, Muraki K and van der Zant H S J 2009 Room-temperature stability of Pt nanogaps formed by self-breaking Appl. Phys. Lett. 94 123108 |
Wheeler P J, Chen R and Natelson D 2013 Noise in electromigrated nanojunctions Phys. Rev. B 87 155411 |
Kanamaru Y, Ando M and Shirakashi J-I 2014 Ultrafast feedback-controlled electromigration using a field-programmable gate array J. Vac. Sci. Technol. B 33 02B106 |
Xiang A, Hou S and Liao J 2014 Tuning the local temperature during feedback controlled electromigration in gold nanowires Appl. Phys. Lett. 104 223113 |
Rothemund P, Morris Bowers C, Suo Z and Whitesides G M 2018 Influence of the contact area on the current density across molecular tunneling junctions measured with EGaIn top-electrodes Chem. Mater. 30 129–37 |
Karuppannan S K, Hongting H, Troadec C, Vilan A and Nijhuis C A 2019 Ultrasmooth and photoresist-free micropore-based EGaIn molecular junctions: fabrication and how roughness determines voltage response Adv. Funct. Mater. 29 1904452 |
Nijhuis C A, Reus W F, Barber J R, Dickey M D and Whitesides G M 2010 Charge transport and rectification in arrays of SAM-based tunneling junctions Nano Lett. 10 3611–9 |
Nijhuis C A, Reus W F, Barber J R and Whitesides G M 2012 Comparison of SAM-based junctions with Ga2O3/EGaIn top electrodes to other large-area tunneling junctions J. Phys. Chem. C 116 14139–50 |
Wan A, Jiang L, Sangeeth C S S and Nijhuis C A 2014 Reversible soft top-contacts to yield molecular junctions with precise and reproducible electrical characteristics Adv. Funct. Mater. 24 4442–56 |
Zhu Z, Daniel T A, Maitani M, Cabarcos O M, Allara D L and Winograd N 2006 Controlling gold atom penetration through alkanethiolate self-assembled monolayers on Au{111} by adjusting terminal group intermolecular interactions J. Am. Chem. Soc. 128 13710–9 |
Kim T-W, Wang G, Lee H and Lee T 2007 Statistical analysis of electronic properties of alkanethiols in metal–molecule–metal junctions Nanotechnology 18 315204 |
Haick H and Cahen D 2008 Contacting organic molecules by soft methods: towards molecule-based electronic devices Acc. Chem. Res. 41 359–66 |
Ulgut B and Abruña H D 2008 Electron transfer through molecules and assemblies at electrode surfaces Chem. Rev. 108 2721–36 |
Khoshmanesh K, Tang S-Y, Zhu J Y, Schaefer S, Mitchell A, Kalantar-zadeh K and Dickey M D 2017 Liquid metal enabled microfluidics Lab Chip 17 974–93 |
Peng Z-L, Chen Z-B, Zhou X-Y, Sun -Y-Y, Liang J-H, Niu Z-J, Zhou X-S and Mao B-W 2012 Single molecule conductance of carboxylic acids contacting Ag and Cu electrodes J. Phys. Chem. C 116 21699–705 |
Aradhya S V, Frei M, Halbritter A and Venkataraman L 2013 Correlating structure, conductance, and mechanics of silver atomic-scale contacts ACS Nano 7 3706–12 |
Ternes M, González C, Lutz C P, Hapala P, Giessibl F J, Jelínek P and Heinrich A J 2011 Interplay of conductance, force, and structural change in metallic point contacts Phys. Rev. Lett. 106 016802 |
Li X et al 2009 Large-area synthesis of high-quality and uniform graphene films on copper foils Science 324 1312 |
Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V and Firsov A A 2004 Electric field effect in atomically thin carbon films Science 306 666 |
Dai H 2002 Carbon nanotubes: synthesis, integration, and properties Acc. Chem. Res. 35 1035–44 |
Avouris P 2002 Molecular electronics with carbon nanotubes Acc. Chem. Res. 35 1026–34 |
Tsukagoshi K, Yagi I and Aoyagi Y 2004 Pentacene nanotransistor with carbon nanotube electrodes Appl. Phys. Lett. 85 1021–3 |
Collins P G, Hersam M, Arnold M, Martel R and Avouris P 2001 Current saturation and electrical breakdown in multiwalled carbon nanotubes Phys. Rev. Lett. 86 3128–31 |
Javey A, Guo J, Paulsson M, Wang Q, Mann D, Lundstrom M and Dai H 2004 High-field quasiballistic transport in short carbon nanotubes Phys. Rev. Lett. 92 106804 |
Collins P G, Arnold M S and Avouris P 2001 Engineering carbon nanotubes and nanotube circuits using electrical breakdown Science 292 706–9 |
Whalley A C, Steigerwald M L, Guo X and Nuckolls C 2007 Reversible switching in molecular electronic devices J. Am. Chem. Soc. 129 12590–1 |
Thiele C et al 2014 Fabrication of carbon nanotube nanogap electrodes by helium ion sputtering for molecular contacts Appl. Phys. Lett. 104 103102 |
Roy S, Vedala H, Roy A D, Kim D-H, Doud M, Mathee K, Shin H-K, Shimamoto N, Prasad V and Choi W 2008 Direct electrical measurements on single-molecule genomic DNA using single-walled carbon nanotubes Nano Lett. 8 26–30 |
Geim A K and Novoselov K S 2007 The rise of graphene Nat. Mater. 6 183–91 |
Nef C, Pósa L, Makk P, Fu W, Halbritter A, Schönenberger C and Calame M 2014 High-yield fabrication of nm-size gaps in monolayer CVD graphene Nanoscale 6 7249–54 |
Mol J A, Lau C S, Lewis W J M, Sadeghi H, Roche C, Cnossen A, Warner J H, Lambert C J, Anderson H L and Briggs G A D 2015 Graphene-porphyrin single-molecule transistors Nanoscale 7 13181–5 |
Sadeghi H, Mol J A, Lau C S, Briggs G A D, Warner J and Lambert C J 2015 Conductance enlargement in picoscale electroburnt graphene nanojunctions Proc. Natl Acad. Sci. USA 112 2658 |
Lau C S, Mol J A, Warner J H and Briggs G A D 2014 Nanoscale control of graphene electrodes Phys. Chem. Chem. Phys. 16 20398–401 |
Zhu Y, Tan Z and Hong W 2021 Simultaneous electrical and mechanical characterization of single-molecule junctions using AFM-BJ technique ACS Omega 6 30873–88 |
Zhou X-S, Liang J-H, Chen Z-B and Mao B-W 2011 An electrochemical jump-to-contact STM-break junction approach to construct single molecular junctions with different metallic electrodes Electrochem. Commun. 13 407–10 |
Wang Y-H, Zhou X-Y, Sun -Y-Y, Han D, Zheng J-F, Niu Z-J and Zhou X-S 2014 Conductance measurement of carboxylic acids binding to palladium nanoclusters by electrochemical jump-to-contact STM break junction Electrochim. Acta 123 205–10 |
Li X-M, Wang Y-H, Seng J-W, Zheng J-F, Cao R, Shao Y, Chen J-Z, Li J-F, Zhou X-S and Mao B-W 2021 z-Piezo pulse-modulated STM break junction: toward single-molecule rectifiers with dissimilar metal electrodes ACS Appl. Mat. Interfaces 13 8656–63 |
Vezzoli A, Brooke R J, Ferri N, Brooke C, Higgins S J, Schwarzacher W and Nichols R J 2018 Charge transport at a molecular GaAs nanoscale junction Faraday Discuss. 210 397–408 |
Vezzoli A, Brooke R J, Ferri N, Higgins S J, Schwarzacher W and Nichols R J 2017 Single-molecule transport at a rectifying GaAs contact Nano Lett. 17 1109–15 |
Vezzoli A, Brooke R J, Higgins S J, Schwarzacher W and Nichols R J 2017 Single-molecule photocurrent at a metal–molecule–semiconductor junction Nano Lett. 17 6702–7 |
Aragonès A C, Darwish N, Ciampi S, Sanz F, Gooding J J and Díez-Pérez I 2017 Single-molecule electrical contacts on silicon electrodes under ambient conditions Nat. Commun. 8 15056 |
Peiris C R, Ciampi S, Dief E M, Zhang J, Canfield P J, Le Brun A P, Kosov D S, Reimers J R and Darwish N 2020 Spontaneous S–Si bonding of alkanethiols to Si(111)–H: towards Si–molecule–Si circuits Chem. Sci. 11 5246–56 |
Peiris C R, Vogel Y B, Le Brun A P, Aragonès A C, Coote M L, Díez-Pérez I, Ciampi S and Darwish N 2019 Metal–single-molecule–semiconductor junctions formed by a radical reaction bridging gold and silicon electrodes J. Am. Chem. Soc. 141 14788–97 |
Kim T, Liu Z-F, Lee C, Neaton J B and Venkataraman L 2014 Charge transport and rectification in molecular junctions formed with carbon-based electrodes Proc. Natl Acad. Sci. USA 111 10928 |
Rudnev A V, Kaliginedi V, Droghetti A, Ozawa H, Kuzume A, Haga M-A, Broekmann P and Rungger I 2017 Stable anchoring chemistry for room temperature charge transport through graphite-molecule contacts Sci. Adv. 3 e1602297 |
Liu L et al 2016 Charge transport through dicarboxylic-acid-terminated alkanes bound to graphene–gold nanogap electrodes Nanoscale 8 14507–13 |
Tao S et al 2019 Graphene-contacted single molecular junctions with conjugated molecular wires ACS Appl. Nano Mater. 2 12–18 |
Zhang Q, Liu L, Tao S, Wang C, Zhao C, González C, Dappe Y J, Nichols R J and Yang L 2016 Graphene as a promising electrode for low-current attenuation in nonsymmetric molecular junctions Nano Lett. 16 6534–40 |
He C, Zhang Q, Fan Y, Zhao C, Zhao C, Ye J, Dappe Y J, Nichols R J and Yang L 2019 Effect of asymmetric anchoring groups on electronic transport in hybrid metal/molecule/graphene single molecule junctions ChemPhysChem 20 1830–6 |
He C, Zhang Q, Gao T, Liu C, Chen Z, Zhao C, Zhao C, Nichols R J, Dappe Y J and Yang L 2020 Charge transport in hybrid platinum/molecule/graphene single molecule junctions Phys. Chem. Chem. Phys. 22 13498–504 |
He C, Zhang Q, Tao S, Zhao C, Zhao C, Su W, Dappe Y J, Nichols R J and Yang L 2018 Carbon-contacted single molecule electrical junctions Phys. Chem. Chem. Phys. 20 24553–60 |
Xiang D, Jeong H, Lee T and Mayer D 2013 Mechanically controllable break junctions for molecular electronics Adv. Mater. 25 4845–67 |
Moreland J and Ekin J W 1985 Electron tunneling experiments using Nb-Sn ‘break’ junctions J. Appl. Phys. 58 3888–95 |
Muller C J, van Ruitenbeek J M and de Jongh L J 1992 Experimental observation of the transition from weak link to tunnel junction Physica C 191 485–504 |
Muller C J, van Ruitenbeek J M and de Jongh L J 1992 Conductance and supercurrent discontinuities in atomic-scale metallic constrictions of variable width Phys. Rev. Lett. 69 140–3 |
Li R et al 2017 Switching of charge transport pathways via delocalization changes in single-molecule metallacycles junctions J. Am. Chem. Soc. 139 14344–7 |
Liu J et al 2017 Radical-enhanced charge transport in single-molecule phenothiazine electrical junctions Angew. Chem., Int. Ed. 56 13061–5 |
Boussaad S and Tao N J 2002 Atom-size gaps and contacts between electrodes fabricated with a self-terminated electrochemical method Appl. Phys. Lett. 80 2398–400 |
He H X, Boussaad S, Xu B Q, Li C Z and Tao N J 2002 Electrochemical fabrication of atomically thin metallic wires and electrodes separated with molecular-scale gaps J. Electroanal. Chem. 522 167–72 |
Li C Z, He H X and Tao N J 2000 Quantized tunneling current in the metallic nanogaps formed by electrodeposition and etching Appl. Phys. Lett. 77 3995–7 |
Liu B, Xiang J, Tian J-H, Zhong C, Mao B-W, Yang F-Z, Chen Z-B, Wu S-T and Tian Z-Q 2005 Controllable nanogap fabrication on microchip by chronopotentiometry Electrochim. Acta 50 3041–7 |
Mészáros G, Kronholz S, Karthäuser S, Mayer D and Wandlowski T 2007 Electrochemical fabrication and characterization of nanocontacts and nm-sized gaps Appl. Phys. A 87 569–75 |
Tian J-H et al 2010 The fabrication and characterization of adjustable nanogaps between gold electrodes on chip for electrical measurement of single molecules Nanotechnology 21 274012 |
Yang Y, Chen Z, Liu J, Lu M, Yang D, Yang F and Tian Z 2011 An electrochemically assisted mechanically controllable break junction approach for single molecule junction conductance measurements Nano Res. 4 1199–207 |
Yang Y, Liu J, Feng S, Wen H, Tian J, Zheng J, Schöllhorn B, Amatore C, Chen Z and Tian Z 2016 Unexpected current–voltage characteristics of mechanically modulated atomic contacts with the presence of molecular junctions in an electrochemically assisted–MCBJ Nano Res. 9 560–70 |
Zheng J-T et al 2016 Electrochemically assisted mechanically controllable break junction studies on the stacking configurations of oligo(phenylene ethynylene)s molecular junctions Electrochim. Acta 200 268–75 |
Yang Y et al 2011 Conductance histogram evolution of an EC–MCBJ fabricated Au atomic point contact Nanotechnology 22 275313 |
Yi Z, Banzet M, Offenhäusser A and Mayer D 2010 Fabrication of nanogaps with modified morphology by potential-controlled gold deposition Phys. Status Solidi 4 73–75 |
van Ruitenbeek J M, Alvarez A, Piñeyro I, Grahmann C, Joyez P, Devoret M H, Esteve D and Urbina C 1996 Adjustable nanofabricated atomic size contacts Rev. Sci. Instrum. 67 108–11 |
Arroyo C R, Frisenda R, Moth-Poulsen K, Seldenthuis J S, Bjørnholm T and van der Zant H S J 2013 Quantum interference effects at room temperature in OPV-based single-molecule junctions Nanoscale Res. Lett. 8 234 |
Kim Y et al 2012 Charge transport characteristics of diarylethene photoswitching single-molecule junctions Nano Lett. 12 3736–42 |
Schirm C, Matt M, Pauly F, Cuevas J C, Nielaba P and Scheer E 2013 A current-driven single-atom memory Nat. Nanotechnol. 8 645–8 |
Stefani D, Guo C, Ornago L, Cabosart D, El Abbassi M, Sheves M, Cahen D and van der Zant H S J 2021 Conformation-dependent charge transport through short peptides Nanoscale 13 3002–9 |
Zhang S et al 2021 In-situ control of on-chip angstrom gaps, atomic switches, and molecular junctions by light irradiation Nano Today 39 101226 |
Yang Y, Liu J, Zheng J, Lu M, Shi J, Hong W, Yang F and Tian Z 2017 Promising electroplating solution for facile fabrication of Cu quantum point contacts Nano Res. 10 3314–23 |
Tan Z et al 2019 Atomically defined angstrom-scale all-carbon junctions Nat. Commun. 10 1748 |
Zhao S et al 2020 Cross-plane transport in a single-molecule two-dimensional van der Waals heterojunction Sci. Adv. 6 eaba6714 |
Champagne A R, Pasupathy A N and Ralph D C 2005 Mechanically adjustable and electrically gated single-molecule transistors Nano Lett. 5 305–8 |
Martin C A, Smit R H M, van der Zant H S J and van Ruitenbeek J M 2009 A nanoelectromechanical single-atom switch Nano Lett. 9 2940–5 |
Martin C A, van Ruitenbeek J M and van der Zant H S J 2010 Sandwich-type gated mechanical break junctions Nanotechnology 21 265201 |
Perrin M L, Verzijl C J O, Martin C A, Shaikh A J, Eelkema R, van Esch J H, van Ruitenbeek J M, Thijssen J M, van der Zant H S J and Duli´ c D 2013 Large tunable image-charge effects in single-molecule junctions Nat. Nanotechnol. 8 282–7 |
Mangin A, Anthore A, Della Rocca M L, Boulat E and Lafarge P 2009 Transport through metallic nanogaps in an in-plane three-terminal geometry J. Appl. Phys. 105 014313 |
Xiang D, Jeong H, Kim D, Lee T, Cheng Y, Wang Q and Mayer D 2013 Three-terminal single-molecule junctions formed by mechanically controllable break junctions with side gating Nano Lett. 13 2809–13 |
Arima A, Tsutsui M, Morikawa T, Yokota K and Taniguchi M 2014 Fabrications of insulator-protected nanometer-sized electrode gaps J. Appl. Phys. 115 114310 |
Muthusubramanian N, Galan E, Maity C, Eelkema R, Grozema F C and van der Zant H S J 2016 Insulator-protected mechanically controlled break junctions for measuring single-molecule conductance in aqueous environments Appl. Phys. Lett. 109 013102 |
Zhao Z, Guo C, Ni L, Zhao X, Zhang S and Xiang D 2021 In situ photoconductivity measurements of imidazole in optical fiber break-junctions Nanoscale Horiz. 6 386–92 |
Benner D, Boneberg J, Nürnberger P, Waitz R, Leiderer P and Scheer E 2014 Lateral and temporal dependence of the transport through an atomic gold contact under light irradiation: signature of propagating surface plasmon polaritons Nano Lett. 14 5218–23 |
Fischer A C, Forsberg F, Lapisa M, Bleiker S J, Stemme G, Roxhed N and Niklaus F 2015 Integrating MEMS and ICs Microsyst. Nanoeng. 1 15005 |
Karipidou Z et al 2016 Ultrarobust thin-film devices from self-assembled metal–terpyridine oligomers Adv. Mater. 28 3473–80 |
Kushmerick J G, Naciri J, Yang J C and Shashidhar R 2003 Conductance scaling of molecular wires in parallel Nano Lett. 3 897–900 |
Snider G, Kuekes P, Hogg T and Williams R S 2005 Nanoelectronic architectures Appl. Phys. A 80 1183–95 |
Stan M R, Franzon P D, Goldstein S C, Lach J C and Ziegler M M 2003 Molecular electronics: from devices and interconnect to circuits and architecture Proc. IEEE 91 1940–57 |
Green J E et al 2007 A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetre Nature 445 414–7 |
Park S, Wang G, Cho B, Kim Y, Song S, Ji Y, Yoon M-H and Lee T 2012 Flexible molecular-scale electronic devices Nat. Nanotechnol. 7 438–42 |
Morteza Najarian A, Szeto B, Tefashe U M and McCreery R L 2016 Robust all-carbon molecular junctions on flexible or semi-transparent substrates using ‘process-friendly’ fabrication ACS Nano 10 8918–28 |
Puebla-Hellmann G, Venkatesan K, Mayor M and Lörtscher E 2018 Metallic nanoparticle contacts for high-yield, ambient-stable molecular-monolayer devices Nature 559 232–5 |
Kos D, Assumpcao D R, Guo C and Baumberg J J 2021 Quantum tunneling induced optical rectification and plasmon-enhanced photocurrent in nanocavity molecular junctions ACS Nano 15 14535–43 |
Wan A, Suchand Sangeeth C S, Wang L, Yuan L, Jiang L and Nijhuis C A 2015 Arrays of high quality SAM-based junctions and their application in molecular diode based logic Nanoscale 7 19547–56 |
Luo Y et al 2002 Two-dimensional molecular electronics circuits ChemPhysChem 3 519–25 |
Melosh N A, Boukai A, Diana F, Gerardot B, Badolato A, Petroff P M and Heath J R 2003 Ultrahigh-density nanowire lattices and circuits Science 300 112–5 |
Kaliginedi V, Moreno-García P, Valkenier H, Hong W, García-Suárez V M, Buiter P, Otten J L H, Hummelen J C, Lambert C J and Wandlowski T 2012 Correlations between molecular structure and single-junction conductance: a case study with oligo(phenylene-ethynylene)-type wires J. Am. Chem. Soc. 134 5262–75 |
Huang C, Rudnev A V, Hong W and Wandlowski T 2015 Break junction under electrochemical gating: testbed for single-molecule electronics Chem. Soc. Rev. 44 889–901 |
Choi S H, Risko C, Delgado M C R, Kim B, Brédas J-L and Frisbie C D 2010 Transition from tunneling to hopping transport in long, conjugated oligo-imine wires connected to metals J. Am. Chem. Soc. 132 4358–68 |
Hines T, Diez-Perez I, Hihath J, Liu H, Wang Z-S, Zhao J, Zhou G, Müllen K and Tao N 2010 Transition from tunneling to hopping in single molecular junctions by measuring length and temperature dependence J. Am. Chem. Soc. 132 11658–64 |
Ho Choi S, Kim B and Frisbie C D 2008 Electrical resistance of long conjugated molecular wires Science 320 1482–6 |
Lu Q, Liu K, Zhang H, Du Z, Wang X and Wang F 2009 From tunneling to hopping: a comprehensive investigation of charge transport mechanism in molecular junctions based on oligo(p-phenylene ethynylene)s ACS Nano 3 3861–8 |
Moreno-García P et al 2013 Single-molecule conductance of functionalized oligoynes: length dependence and junction evolution J. Am. Chem. Soc. 135 12228–40 |
Zhao X, Huang C, Gulcur M, Batsanov A S, Baghernejad M, Hong W, Bryce M R and Wandlowski T 2013 Oligo(aryleneethynylene)s with terminal pyridyl groups: synthesis and length dependence of the tunneling-to-hopping transition of single-molecule conductances Chem. Mater. 25 4340–7 |
Wang W, Lee T and Reed M A 2003 Mechanism of electron conduction in self-assembled alkanethiol monolayer devices Phys. Rev. B 68 035416 |
Venkataraman L, Klare J E, Tam I W, Nuckolls C, Hybertsen M S and Steigerwald M L 2006 Single-molecule circuits with well-defined molecular conductance Nano Lett. 6 458–62 |
Li X, He J, Hihath J, Xu B, Lindsay S M and Tao N 2006 Conductance of single alkanedithiols: conduction mechanism and effect of molecule−electrode contacts J. Am. Chem. Soc. 128 2135–41 |
Park Y S, Whalley A C, Kamenetska M, Steigerwald M L, Hybertsen M S, Nuckolls C and Venkataraman L 2007 Contact chemistry and single-molecule conductance: a comparison of phosphines, methyl sulfides, and amines J. Am. Chem. Soc. 129 15768–9 |
Quinn J R, Foss F W, Venkataraman L and Breslow R 2007 Oxidation potentials correlate with conductivities of aromatic molecular wires J. Am. Chem. Soc. 129 12376–7 |
Liu K, Wang X and Wang F 2008 Probing charge transport of ruthenium-complex-based molecular wires at the single-molecule level ACS Nano 2 2315–23 |
Wen H-M, Yang Y, Zhou X-S, Liu J-Y, Zhang D-B, Chen Z-B, Wang J-Y, Chen Z-N and Tian Z-Q 2013 Electrical conductance study on 1,3-butadiyne-linked dinuclear ruthenium(ii) complexes within single molecule break junctions Chem. Sci. 4 2471–7 |
Algethami N, Sadeghi H, Sangtarash S and Lambert C J 2018 The conductance of porphyrin-based molecular nanowires increases with length Nano Lett. 18 4482–6 |
Capozzi B, Chen Q, Darancet P, Kotiuga M, Buzzeo M, Neaton J B, Nuckolls C and Venkataraman L 2014 Tunable charge transport in single-molecule junctions via electrolytic gating Nano Lett. 14 1400–4 |
Li C, Pobelov I, Wandlowski T, Bagrets A, Arnold A and Evers F 2008 Charge transport in single Au | alkanedithiol | Au junctions: coordination geometries and conformational degrees of freedom J. Am. Chem. Soc. 130 318–26 |
Quek S Y, Kamenetska M, Steigerwald M L, Choi H J, Louie S G, Hybertsen M S, Neaton J B and Venkataraman L 2009 Mechanically controlled binary conductance switching of a single-molecule junction Nat. Nanotechnol. 4 230–4 |
Vonlanthen D, Mishchenko A, Elbing M, Neuburger M, Wandlowski T and Mayor M 2009 Chemically controlled conductivity: torsion-angle dependence in a single-molecule biphenyldithiol junction Angew. Chem., Int. Ed. 48 8886–90 |
You S, J-T L, Guo J and Jiang Y 2017 Recent advances in inelastic electron tunneling spectroscopy Adv. Phys. X 2 907–36 |
Smit R H M, Noat Y, Untiedt C, Lang N D, van Hemert M C and van Ruitenbeek J M 2002 Measurement of the conductance of a hydrogen molecule Nature 419 906–9 |
Stipe B C, Rezaei M A and Ho W 1998 Single-molecule vibrational spectroscopy and microscopy Science 280 1732–5 |
Kim Y, Song H, Strigl F, Pernau H-F, Lee T and Scheer E 2011 Conductance and vibrational states of single-molecule junctions controlled by mechanical stretching and material variation Phys. Rev. Lett. 106 196804 |
Long D P, Lazorcik J L, Mantooth B A, Moore M H, Ratner M A, Troisi A, Yao Y, Ciszek J W, Tour J M and Shashidhar R 2006 Effects of hydration on molecular junction transport Nat. Mater. 5 901–8 |
Konishi T, Kiguchi M, Takase M, Nagasawa F, Nabika H, Ikeda K, Uosaki K, Ueno K, Misawa H and Murakoshi K 2013 Single molecule dynamics at a mechanically controllable break junction in solution at room temperature J. Am. Chem. Soc. 135 1009–14 |
Ward D R, Halas N J, Ciszek J W, Tour J M, Wu Y, Nordlander P and Natelson D 2008 Simultaneous measurements of electronic conduction and Raman response in molecular junctions Nano Lett. 8 919–24 |
Yoon H P, Maitani M M, Cabarcos O M, Cai L, Mayer T S and Allara D L 2010 Crossed-nanowire molecular junctions: a new multispectroscopy platform for conduction−structure correlations Nano Lett. 10 2897–902 |
de Nijs B et al 2017 Plasmonic tunnel junctions for single-molecule redox chemistry Nat. Commun. 8 994 |
Guo C et al 2018 Molecular orbital gating surface-enhanced Raman scattering ACS Nano 12 11229–35 |
Zhao Z et al 2018 Shaping the atomic-scale geometries of electrodes to control optical and electrical performance of molecular devices Small 14 1703815 |
Bi H, Palma C-A, Gong Y, Hasch P, Elbing M, Mayor M, Reichert J and Barth J V 2018 Voltage-driven conformational switching with distinct Raman signature in a single-molecule junction J. Am. Chem. Soc. 140 4835–40 |
Kos D, Di Martino G, Boehmke A, de Nijs B, Berta D, Földes T, Sangtarash S, Rosta E, Sadeghi H and Baumberg J J 2020 Optical probes of molecules as nano-mechanical switches Nat. Commun. 11 5905 |
Domulevicz L, Jeong H, Paul N K, Gomez-Diaz J S and Hihath J 2021 Multidimensional characterization of single-molecule dynamics in a plasmonic nanocavity Angew. Chem., Int. Ed. 60 16436–41 |
Ludoph B and Ruitenbeek J M V 1999 Thermopower of atomic-size metallic contacts Phys. Rev. B 59 12290–3 |
Reddy P, Jang S-Y, Segalman Rachel A and Majumdar A 2007 Thermoelectricity in molecular junctions Science 315 1568–71 |
Tan A, Sadat S and Reddy P 2010 Measurement of thermopower and current-voltage characteristics of molecular junctions to identify orbital alignment Appl. Phys. Lett. 96 013110 |
Elbing M, Ochs R, Koentopp M, Fischer M, von Hänisch C, Weigend F, Evers F, Weber H B and Mayor M 2005 A single-molecule diode Proc. Natl Acad. Sci. USA 102 8815 |
Batra A, Darancet P, Chen Q, Meisner J S, Widawsky J R, Neaton J B, Nuckolls C and Venkataraman L 2013 Tuning rectification in single-molecular diodes Nano Lett. 13 6233–7 |
Capozzi B, Xia J, Adak O, Dell E J, Liu Z-F, Taylor J C, Neaton J B, Campos L M and Venkataraman L 2015 Single-molecule diodes with high rectification ratios through environmental control Nat. Nanotechnol. 10 522–7 |
Ke G, Duan C, Huang F and Guo X 2020 Electrical and spin switches in single-molecule junctions InfoMat 2 92–112 |
Song H, Reed M A and Lee T 2011 Single molecule electronic devices Adv. Mater. 23 1583–608 |
Duli´ c D, van der Molen S J, Kudernac T, Jonkman H T, de Jong J J D, Bowden T N, van Esch J, Feringa B L and van Wees B J 2003 One-way optoelectronic switching of photochromic molecules on gold Phys. Rev. Lett. 91 207402 |
Odell A, Delin A, Johansson B, Rungger I and Sanvito S 2010 Investigation of the conducting properties of a photoswitching dithienylethene molecule ACS Nano 4 2635–42 |
Pärs M, Hofmann C C, Willinger K, Bauer P, Thelakkat M and Köhler J 2011 An organic optical transistor operated under ambient conditions Angew. Chem., Int. Ed. 50 11405–8 |
He J et al 2005 Switching of a photochromic molecule on gold electrodes: single-molecule measurements Nanotechnology 16 695–702 |
Meng F, Hervault Y-M, Shao Q, Hu B, Norel L, Rigaut S and Chen X 2014 Orthogonally modulated molecular transport junctions for resettable electronic logic gates Nat. Commun. 5 3023 |
Cao Y, Dong S, Liu S, Liu Z and Guo X 2013 Toward functional molecular devices based on graphene–molecule junctions Angew. Chem., Int. Ed. 52 3906–10 |
Kumar A S, Ye T, Takami T, Yu B-C, Flatt A K, Tour J M and Weiss P S 2008 Reversible photo-switching of single azobenzene molecules in controlled nanoscale environments Nano Lett. 8 1644–8 |
Pakula C, Zaporojtchenko V, Strunskus T, Zargarani D, Herges R and Faupel F 2010 Reversible light-controlled conductance switching of azobenzene-based metal/polymer nanocomposites Nanotechnology 21 465201 |
Smaali K, Lenfant S, Karpe S, Oçafrain M, Blanchard P, Deresmes D, Godey S, Rochefort A, Roncali J and Vuillaume D 2010 High on−off conductance switching ratio in optically-driven self-assembled conjugated molecular systems ACS Nano 4 2411–21 |
Jia C et al 2016 Covalently bonded single-molecule junctions with stable and reversible photoswitched conductivity Science 352 1443–5 |
Jia C, Wang J, Yao C, Cao Y, Zhong Y, Liu Z, Liu Z and Guo X 2013 Conductance switching and mechanisms in single-molecule junctions Angew. Chem., Int. Ed. 52 8666–70 |
Tsuji Y and Hoffmann R 2014 Frontier orbital control of molecular conductance and its switching Angew. Chem., Int. Ed. 53 4093–7 |
Roldan D, Kaliginedi V, Cobo S, Kolivoska V, Bucher C, Hong W, Royal G and Wandlowski T 2013 Charge transport in photoswitchable dimethyldihydropyrene-type single-molecule junctions J. Am. Chem. Soc. 135 5974–7 |
Broman S L, Lara-Avila S, Thisted C L, Bond A D, Kubatkin S, Danilov A and Nielsen M B 2012 Dihydroazulene photoswitch operating in sequential tunneling regime: synthesis and single-molecule junction studies Adv. Funct. Mater. 22 4249–58 |
Lara-Avila S, Danilov A V, Kubatkin S E, Broman S L, Parker C R and Nielsen M B 2011 Light-triggered conductance switching in single-molecule dihydroazulene/vinylheptafulvene junctions J. Phys. Chem. C 115 18372–7 |
Li T et al 2013 Ultrathin reduced graphene oxide films as transparent top-contacts for light switchable solid-state molecular junctions Adv. Mater. 25 4164–70 |
Seo S, Min M, Lee S M and Lee H 2013 Photo-switchable molecular monolayer anchored between highly transparent and flexible graphene electrodes Nat. Commun. 4 1920 |
Battacharyya S, Kibel A, Kodis G, Liddell P A, Gervaldo M, Gust D and Lindsay S 2011 Optical modulation of molecular conductance Nano Lett. 11 2709–14 |
Orbelli Biroli A et al 2011 A multitechnique physicochemical investigation of various factors controlling the photoaction spectra and of some aspects of the electron transfer for a series of push–pull Zn(II) porphyrins acting as dyes in DSSCs J. Phys. Chem. C 115 23170–82 |
Klajn R 2014 Spiropyran-based dynamic materials Chem. Soc. Rev. 43 148–84 |
Cai S et al 2019 Light-driven reversible intermolecular proton transfer at single-molecule junctions Angew. Chem., Int. Ed. 58 3829–33 |
Zhang X, Hou L and Samor`ı P 2016 Coupling carbon nanomaterials with photochromic molecules for the generation of optically responsive materials Nat. Commun. 7 11118 |
Taniguchi M, Tsutsui M, Yokota K and Kawai T 2010 Mechanically-controllable single molecule switch based on configuration specific electrical conductivity of metal–molecule–metal junctions Chem. Sci. 1 247–53 |
Ferri N, Algethami N, Vezzoli A, Sangtarash S, McLaughlin M, Sadeghi H, Lambert C J, Nichols R J and Higgins S J 2019 Hemilabile ligands as mechanosensitive electrode contacts for molecular electronics Angew. Chem., Int. Ed. 58 16583–9 |
Diez-Perez I, Hihath J, Hines T, Wang Z-S, Zhou G, Müllen K and Tao N 2011 Controlling single-molecule conductance through lateral coupling of π orbitals Nat. Nanotechnol. 6 226–31 |
Meisner J S, Kamenetska M, Krikorian M, Steigerwald M L, Venkataraman L and Nuckolls C 2011 A single-molecule potentiometer Nano Lett. 11 1575–9 |
Wu C, Bates D, Sangtarash S, Ferri N, Thomas A, Higgins S J, Robertson C M, Nichols R J, Sadeghi H and Vezzoli A 2020 Folding a single-molecule junction Nano Lett. 20 7980–6 |
Su T A, Li H, Steigerwald M L, Venkataraman L and Nuckolls C 2015 Stereoelectronic switching in single-molecule junctions Nat. Chem. 7 215–20 |
Franco I, George C B, Solomon G C, Schatz G C and Ratner M A 2011 Mechanically activated molecular switch through single-molecule pulling J. Am. Chem. Soc. 133 2242–9 |
Walkey M C et al 2019 Chemically and mechanically controlled single-molecule switches using spiropyrans ACS Appl. Mat. Interfaces 11 36886–94 |
Bruot C, Hihath J and Tao N 2012 Mechanically controlled molecular orbital alignment in single molecule junctions Nat. Nanotechnol. 7 35–40 |
Li Y, Haworth N L, Xiang L, Ciampi S, Coote M L and Tao N 2017 Mechanical stretching-induced electron-transfer reactions and conductance switching in single molecules J. Am. Chem. Soc. 139 14699–706 |
Stefani D, Weiland K J, Skripnik M, Hsu C, Perrin M L, Mayor M, Pauly F and van der Zant H S J 2018 Large conductance variations in a mechanosensitive single-molecule junction Nano Lett. 18 5981–8 |
Camarasa-Gómez M, Hernangómez-Pérez D, Inkpen M S, Lovat G, Fung E D, Roy X, Venkataraman L and Evers F 2020 Mechanically tunable quantum interference in ferrocene-based single-molecule junctions Nano Lett. 20 6381–6 |
Tang C et al 2020 Electric-field-induced connectivity switching in single-molecule junctions iScience 23 100770 |
Meng L et al 2019 Side-group chemical gating via reversible optical and electric control in a single molecule transistor Nat. Commun. 10 1450 |
Alemani M, Peters M V, Hecht S, Rieder K-H, Moresco F and Grill L 2006 Electric field-induced isomerization of azobenzene by STM J. Am. Chem. Soc. 128 14446–7 |
Li H B, Tebikachew B E, Wiberg C, Moth-Poulsen K and Hihath J 2020 A memristive element based on an electrically controlled single-molecule reaction Angew. Chem., Int. Ed. 59 11641–6 |
Godlewski S, Kawai H, Kolmer M, Zuzak R, Echavarren A M, Joachim C, Szymonski M and Saeys M 2016 Single-molecule rotational switch on a dangling bond dimer bearing ACS Nano 10 8499–507 |
Zhang L et al 2018 Electrochemical and electrostatic cleavage of alkoxyamines J. Am. Chem. Soc. 140 766–74 |
Xin N et al 2021 Tunable symmetry-breaking-induced dual functions in stable and photoswitched single-molecule junctions J. Am. Chem. Soc. 143 20811–7 |
Fahad H M, Hu C and Hussain M M 2015 Simulation study of a 3D device integrating FinFET and UTBFET IEEE Trans. Electron Devices 62 83–87 |
Yadav C, Kushwaha P, Khandelwal S, Duarte J P, Chauhan Y S and Hu C 2014 Modeling of GaN-based normally-off FinFET IEEE Electron Device Lett. 35 612–4 |
Lee B-H, Hur J, Kang M-H, Bang T, Ahn D-C, Lee D, Kim K-H and Choi Y-K 2016 A vertically integrated junctionless nanowire transistor Nano Lett. 16 1840–7 |
Lee B-H, Kang M-H, Ahn D-C, Park J-Y, Bang T, Jeon S-B, Hur J, Lee D and Choi Y-K 2015 Vertically integrated multiple nanowire field effect transistor Nano Lett. 15 8056–61 |
Gaudenzi R, de Bruijckere J, Reta D, Moreira I D P R, Rovira C, Veciana J, van der Zant H S J and Burzurí E 2017 Redox-induced gating of the exchange interactions in a single organic diradical ACS Nano 11 5879–83 |
Hofmeister C, Härtle R, Rubio-Pons O, Coto P B, ´ Sobolewski A L and Thoss M 2014 Switching the conductance of a molecular junction using a proton transfer reaction J. Mol. Model. 20 2163 |
Weckbecker D, Coto P B and Thoss M 2021 Molecular transistor controlled through proton transfer J. Phys. Chem. Lett. 12 413–7 |
Zhang J, Kuznetsov A M, Medvedev I G, Chi Q, Albrecht T, Jensen P S and Ulstrup J 2008 Single-molecule electron transfer in electrochemical environments Chem. Rev. 108 2737–91 |
Lovat G, Choi B, Paley D W, Steigerwald M L, Venkataraman L and Roy X 2017 Room-temperature current blockade in atomically defined single-cluster junctions Nat. Nanotechnol. 12 1050–4 |
Xin N, Li X, Jia C, Gong Y, Li M, Wang S, Zhang G, Yang J and Guo X 2018 Tuning charge transport in aromatic-ring single-molecule junctions via ionic-liquid gating Angew. Chem., Int. Ed. 57 14026–31 |
Sanvito S 2011 Molecular spintronics Chem. Soc. Rev. 40 3336–55 |
Naaman R and Waldeck D H 2015 Spintronics and chirality: spin selectivity in electron transport through chiral molecules Annu. Rev. Phys. Chem. 66 263–81 |
Senthil Kumar K and Ruben M 2017 Emerging trends in spin crossover (SCO) based functional materials and devices Coord. Chem. Rev. 346 176–205 |
Brooke R J, Jin C, Szumski D S, Nichols R J, Mao B-W, Thygesen K S and Schwarzacher W 2015 Single-molecule electrochemical transistor utilizing a nickel-pyridyl spinterface Nano Lett. 15 275–80 |
Li J, Wu Q, Xu W, Wang H-C, Zhang H, Chen Y, Tang Y, Hou S, Lambert C J and Hong W 2021 Room-temperature single-molecule conductance switch via confined coordination-induced spin-state manipulation CCS Chem. 1744–52 |
Naaman R and Waldeck D H 2012 Chiral-induced spin selectivity effect J. Phys. Chem. Lett. 3 2178–87 |
Suda M, Thathong Y, Promarak V, Kojima H, Nakamura M, Shiraogawa T, Ehara M and Yamamoto H M 2019 Light-driven molecular switch for reconfigurable spin filters Nat. Commun. 10 2455 |
Zou D, Zhao W, Cui B, Li D and Liu D 2018 Adsorption of gas molecules on a manganese phthalocyanine molecular device and its possibility as a gas sensor Phys. Chem. Chem. Phys. 20 2048–56 |
Huang X et al 2019 Electric field–induced selective catalysis of single-molecule reaction Sci. Adv. 5 eaaw3072 |
Moreno-Pineda E, Klyatskaya S, Du P, Damjanovi´ c M, Taran G, Wernsdorfer W and Ruben M 2018 Observation of cooperative electronic quantum tunneling: increasing accessible nuclear states in a molecular qudit Inorg. Chem. 57 9873–9 |
Wernsdorfer W and Ruben M 2019 Synthetic Hilbert space engineering of molecular qudits: isotopologue chemistry Adv. Mater. 31 1806687 |
Winkelmann C B, Roch N, Wernsdorfer W, Bouchiat V and Balestro F 2009 Superconductivity in a single-C60 transistor Nat. Phys. 5 876–9 |
Goswami S et al 2020 Charge disproportionate molecular redox for discrete memristive and memcapacitive switching Nat. Nanotechnol. 15 380–9 |
Thiele S, Balestro F, Ballou R, Klyatskaya S, Ruben M and Wernsdorfer W 2014 Electrically driven nuclear spin resonance in single-molecule magnets Science 344 1135–8 |